Bis(μ-N,N′,N′′-tri-3-pyridylpyridine-1,3,5-tricarboxamide-κ2 N:N′)bis[dichloridomercury(II)] methanol disolvate
نویسندگان
چکیده
The title dinuclear centrosymmetric complex, [Hg(2)Cl(4)(C(24)H(18)N(6)O(3))(2)]·2CH(3)OH, comprises Hg(II) atoms coordinated by two Cl atoms and two N atoms from ligands in a distorted tetra-hedral geometry. The solvent mol-ecules are linked by hydrogen bonds.
منابع مشابه
catena-Poly[[[bis(O,O′-diisobutyl dithiophosphato-κ2 S,S′)nickel(II)]-μ-1,2-bis(4-pyridylmethylene)hydrazine-κ2 N:N′] toluene disolvate]
The polymeric title compound, {[Ni(C(8)H(18)O(2)PS(2))(2)(C(12)H(10)N(4))]·2C(7)H(7)}(n), has a linear topology and features octa-hedrally coordinated Ni atoms with a trans-N(2)S(4) donor set. The toluene solvent mol-ecules occupy channels defined by the three-dimensional stacking of the polymeric chains. The Ni atom is located at a centre of inversion and the bridging 1,2-bis-(4-pyridylmethyl-...
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In the dinuclear centrosymmetric title complex, [Hg(2)Br(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, the Hg(II) atom is coordinated by two Br atoms and two N atoms from two different ligands in a distorted tetra-hedral geometry. The solvent mol-ecule is linked to the 28-atom ring by two hydrogen bonds.
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In the title compound, [Zn(2)Cl(4)(C(22)H(18)N(4))(2)]·2C(3)H(7)NO, the 1,3-bis-[(benzimidazol-1-yl)meth-yl]benzene ligand bridges two ZnCl(2) units, forming a centrosymmetric dinuclear mol-ecule. The Zn(II) atom shows a distorted tetra-hedral coordination within a Cl(2)N(2) donor set.
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In the title polymeric complex, {[Fe(C12H10N2)2(H2O)4](CH3C6H4SO3)2·2CH3OH} n , the FeII cation, located on an inversion centre, is coordinated by four water mol-ecules in the equatorial positions and two 1,2-bis-(pyridin-4-yl)ethene mol-ecules in the axial positions. This results in a distorted octa-hedral geometry for the [N2O4] coordination polyhedron. The 1,2-bis-(pyridin-4-yl)ethene mol-ec...
متن کاملBis(μ-N,N′-di-3-pyridylpyridine-2,6-dicarboxamide)bis[dichloridomercury(II)] N,N-dimethylformamide disolvate
The asymmetric unit of the binuclear title complex, [Hg(2)Cl(4)(C(17)H(13)N(5)O(2))(2)]·2C(3)H(7)NO, contains one-half of the centrosymmetric mol-ecule and one dimethyl-formamide solvent mol-ecule. The Hg(II) atom is four-coordinated by two N atoms from two ligands and two Cl atoms in a distorted tetra-hedral coordination geometry. Intra-molecular N-H⋯O hydrogen bonds may be effective in the st...
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